研究成果
我的研究成果
1) Rhodium(II)-Catalyzed [4+3] Cyclization of Triazoles with Indole Derivatives and Its Application in the Total Synthesis of (±)-Aurantioclavine Duan, S.; Xue, B.; Meng, H.; Ye, Z.; Xu, Z.-F.; Li, C.-Y.* Chin. J. Chem. 2021, 39, 1145-1152.
2) Asymmetric Synthesis and Application of Chiral Spirosilabiindanes Chang, X.; Ma, P.-L.; Chen, H.-C.; Li C.-Y.*, Wang, P.* Angew. Chem., Int. Ed. 2020, 59, 8937-8940.
3) Synthesis of Cyclopenta[b]indoles via a Formal [3 + 2] Cyclization of N-Sulfonyl-1,2,3-triazoles and Indoles Duan, S.; Zhang, W.; Hu, Y.; Xu, Z.-F.; Li, C.-Y.* Adv. Synth. Catal. 2020, 362, 3570-3575.
4) Synthesis of α-(2-Hydroxyphenyl)-α-Aminoketones by Rhodium-Catalyzed Tandem Reaction of 1-Sulfonyl-1,2,3-Triazoles and Benzoquinone-Derived Alcohols Xu, Z.-F. *; Wang, W.; Cen, M.; Feng, Z.; Duan, S.; Li, C.-Y.* Adv. Synth. Catal. 2020, 362, 2888-2893.
5) Synthesis of Cyclopropanes via 1,3-Migration of Acyloxy Groups Triggered by Formation of α-Imino Rhodium Carbenes Xu, Z.-F. *; Liu, J.; Chang, X.; Chen, T.; Xu, H.; Duan, S.; Li, C.-Y.* Org. Lett. 2020, 22, 5163-5169.
6) Synthesis of Pyrido[2,3-b]indole Derivatives via Rhodium-Catalyzed Cyclization of Indoles and 1-Sulfonyl-1,2,3-Triazoles Duan, S.; An, Y.; Xue, B.; Chen, Y.; Zhang, W.; Xu, Z.-F.; Li, C.-Y.* Adv. Synth. Catal. 2020, 362, 1831-1835.
7) Synthesis of α-cyano sulfone via thermal rearrangement of 1,4-disubstituted triazole mediated by carbene and radical species Cen, M.; Xiang, Q.; Xu, Y.; Duan, S.; Lv, Y.; Xu, Z.-F.*; Li, C.-Y.* Org. Chem. Front. 2020, 7, 596-601.
8) Synthesis of α-aminoketones from N-sulfonyl-1,2,3-triazoles via N-sulfinyl imines generated by intramolecular oxygen transfer Xu, Z.-F.; Shan, L.; Zhang, W.; Cen, M.; Li, C.-Y.* Org. Chem. Front. 2019, 6, 1391-1396.
9) Synthesis of Piperidine Derivatives by Rhodium- Catalyzed Tandem Reaction of N-Sulfonyl-1,2,3-Triazole and Vinyl Ether Yu, S.; An, Y.; Wang, W.; Xu, Z.-F. *; Li, C.-Y.* Adv. Synth. Catal. 2018, 360, 2125-2130.
10) Metal-Free Synthesis of Imidazole by BF3·Et2O Promoted Denitrogenative Transannulation of N-Sulfonyl-1,2,3-triazole Yang, D.; Shan, L.; Xu, Z.-F. *; Li, C.-Y. * Org. Biomol. Chem. 2018, 16, 1461-1464.
11) Metal-Free Synthesis of (E)‑Monofluoroenamine from 1‑Sulfonyl-1,2,3-triazole and Et2O·BF3 via Stereospecific Fluorination of α‑Diazoimine Xu, Z.-F.; Dai, H.; Shan, L.; Li, C.-Y. * Org. Lett. 2018, 20, 1054-1057.
12) Rhodium-Catalyzed Synthesis of 1,2-Dihydropyridine by Tandem Reaction of 4-(1-Acetoxyallyl)-1-sulfonyl-1,2,3-triazole Dai, H.; Yu, S.; Cheng, W.; Xu, Z.-F.*; Li, C.-Y. * Chem. Commun. 2017, 53, 6417-6420.
13) Metal-free synthesis of 2-aminonaphthalenes by intramolecular transannulation of 1-sulfonyl-4(2-alkenylphenyl)-1,2,3-triazoles Xu, Z.-F.; Yu, X.; Yang, D.; Li, C.-Y. * Org. Biomol. Chem. 2017, 15, 3161-3164.
14) Synthesis of Multifunctionalized 2‑Carbonylpyrrole by Rhodium-Catalyzed Transannulation of 1‑Sulfonyl-1,2,3-triazole with β‑Diketone Cheng, W.; Tang, Y.; Xu, Z.-F.*; Li, C.-Y. * Org. Lett. 2016, 18, 6168-6171.
15) Synthesis of 5‑Iodo-1,2,3,4-tetrahydropyridines by Rhodium-Catalyzed Tandem Nucleophilic Attacks Involving 1‑Sulfonyl-1,2,3-triazoles and Iodides Man, Z.; Dai, H.; Shi, Y.; Yang, D.; Li, C.-Y. * Org. Lett. 2016, 18, 4962-4965.
16) Rhodium-Catalyzed Synthesis of 4-Bromo-1,2-dihydroisoquinolines: Access to Bromonium Ylides by the Intramolecular Reaction of a Benzyl Bromide and an α–Imino Carbene He, J.; Shi, Y.; Cheng, W.; Man, Z.; Yang, D.; Li, C.-Y. * Angew. Chem., Int. Ed. 2016, 55, 4557-4561.
17) Rhodium-Catalyzed Synthesis of 2,5-Epoxybenzo[f][1,4]oxazepines via a Tandem Reaction of 1-Sulfonyl-1,2,3-triazoles and Salicylaldehydes Shi, Y.; Yu, X.; Li, C.-Y. * Eur. J. Org. Chem. 2015, 6429-6433.
18) Synthesis of β-Amino-α,β-unsaturated Ketone Derivatives via Sequential Rhodium-Catalyzed Sulfur Ylide Formation/Rearrangement He, J.; Man, Z.; Shi, Y.; Li, C.-Y. * J. Org. Chem. 2015, 80, 4816-4823.
19) Rhodium-Catalyzed Synthesis of Multi-substituted Furans from N-sulfonyl-1,2,3-triazoles Bearing Tethered Carbonyl Group Zhang, W.-B.; Xiu, S.-D.; Li, C.-Y. * Org. Chem. Front. 2015, 2, 47-50.
20) Synthesis of N-Acylamidines via Rhodium-Catalyzed Reaction of Nitrosobenzene Derivatives with N-Sulfonyl-1,2,3-triazoles Ran, R.-Q.; Xiu, S.-D.; Li, C.-Y. * Org. Lett. 2014, 16, 6394-6396.
21) Synthesis of 3-Pyrrolin-2-ones by Rhodium-Catalyzed Transannulation of 1-Sulfonyl-1,2,3-triazole with Ketene Silyl Acetal Ran, R.-Q.; He, J.; Xiu, S.-D.; Wang, K.-B.; Li, C.-Y. * Org. Lett. 2014, 16, 3704-3707.
22) Synthesis of Cyclobutanones via Gold-Catalyzed Oxidative Rearrangement of Homopropargylic Ethers Xu, M.; Ren, T.-T.; Wang, K.-B.; Li, C.-Y.* Adv. Synth. Catal. 2013, 355, 2488-2494.
23) Synthesis of 3-Aza-bicyclo[3.1.0]hexan-2-one Derivatives via Gold-Catalyzed Oxidative Cyclopropanation of N-Allylynamides Wang, K.-B.; Ran, R.-Q.; Xiu, S.-D.; Li, C.-Y. * Org. Lett. 2013, 15, 2374-2377.
24) Synthesis of Oxindole via Gold-Catalyzed Oxidation of N-Arylynamide Yang, L.-Q.; Wang, K.-B.; Li, C.-Y. * Eur. J. Org. Chem. 2013, 2775-2779.
25) Gold-Catalyzed Oxidative Rearrangement of Homopropargylic Ether via Oxonium Ylide Xu, M.; Ren, T.-T.; Li, C.-Y. * Org. Lett. 2012, 14, 4902-4905.
26) Synthesis of Allenes via Gold-Catalyzed Intermolecular Reaction of Propargylic Alcohols and Aromatic Compounds Xu, C.-F.; Xu, M.; Yang, L.-Q.; Li, C.-Y. * J. Org. Chem. 2012, 77, 3010-3016.
27) Gold-Catalyzed Synthesis of Benzil Derivatives and α-Keto Imides via Oxidation of Alkynes Xu, C.-F.; Xu, M.; Jia, Y.-X.; Li, C.-Y. * Org. Lett. 2011, 13, 1556-1559.
